column 7 of the hazardous materials table

Interior heating coils are not authorized. B28 Packagings must be made of stainless steel. The letter Z shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in 178.702(a)(2) of this subchapter to specify the material used for the other packaging. A13 Bulk packagings are not authorized for transportation by aircraft. learn more about the process here. Background and more details are available in the N80 Packages consisting of one inner metal can, not over 2.5 kg (5.5 pounds) capacity, packed in an outer wooden or fiberboard box, or a wooden barrel, are authorized and need not conform to the requirements of part 178 of this subchapter. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. B57 Class 115A tank car tanks used to transport chloroprene must be equipped with a non-reclosing pressure relief device of a diameter not less than 305 mm (12 inches) with a maximum rupture disc pressure of 310 kPa (45 psig). Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 C (115 F). Comparative fire testing between a package as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during testing does not differ by more than 200 C (392 F). 15, 1976, unless otherwise noted. Navigate by entering citations or phrases Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. These substances must satisfy the criteria for classification as an ammonium nitrate emulsion of Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter), and may not be classified and transported unless approved by the Associate Administrator. A current copy of CGA pamphlet, CGA C-6 must be available at the facility servicing the life-saving appliance. The HMT provides the basic information necessary to ship a hazardous material safely. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. A105 a. The letter codes are placed in front of the number codes (for example, "A29"). contact the publishing agency. This content is from the eCFR and is authoritative but unofficial. Displaying title 49, up to date as of 3/02/2023. 365 For manufactured instruments and articles containing mercury, see UN3506. (5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated. 49 CFR 173.24 - LII / Legal Information Institute Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. (c) Tables of special provisions. For Federal Register citations affecting 172.102, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.govinfo.gov. Each IBC may not exceed a maximum net quantity of 1,000 kg: a. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. The tank must have been designed and constructed to be capable of withstanding full vacuum. TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. The presence of a Class 8 hazard must be communicated as required by this part for subsidiary hazards. 52 This entry may only be used for substances that are too insensitive for acceptance into Class 1 (explosive) when tested in accordance with Test Series 2 in the UN Manual of Tests and Criteria, Part I (incorporated by reference; see 171.7 of this subchapter). When the word Normal is indicated, 178.275(g)(3) of this subchapter does not apply. N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. 31 Materials which have undergone sufficient heat treatment to render them non-hazardous are not subject to the requirements of this subchapter. user convenience only and is not intended to alter agency intent Others such as copper and silver are available in trace amounts. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. What is Column 7 of the hazardous materials Table? A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. Fertilizers meeting the criteria for this identification number are only subject to the requirements of this subchapter when offered for transportation and transported by air or vessel. For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). (iv) T75. The operator of an aircraft carrying hazardous materials must do all of the following EXCEPT: A. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. 420 This entry does not apply to manufactured articles (such as table tennis balls). This document is available in the following developer friendly formats: Information and documentation can be found in our 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). (7) A code containing the letter T refers to a special provision which applies only to transportation in UN or IM Specification portable tanks. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. Other inorganic nitrate salts may replace part of the ammonium nitrate. Multiple provisions can be listed in this column. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). Molten sulfur must be marked as required by 172.325 of this subchapter. When a plus sign is assigned to mix- is available with paragraph structure matching the official CFR N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. Overview of Hazardous Material Transportation Regulations Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter. 338 Life Saving appliances, self-inflating transported by motor vehicle only between an U.S. Coast Guard approved inflatable life raft servicing facility and a vessel are only subject to the following requirements: a. The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). Column 7 specifies codes for special provisions applicable to hazardous materials. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. eCFR :: 49 CFR 172.202 -- Description of hazardous material on shipping As a It is not an official legal edition of the CFR. 156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter. 357 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the crude oil can present an inhalation hazard must be marked as specified in 172.327 of this part. 123 Any explosives, blasting, type C containing chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts. This provision may be used for both domestic and international shipments. Special provisions contain packaging provisions, prohibitions, exceptions from requirements for particular quantities or forms of materials and requirements or prohibitions applicable to specific modes of transportation, as follows: (1) A code consisting only of numbers (for example, 11) is multi-modal in application and may apply to bulk and non-bulk packagings. 26 This entry does not include ammonium permanganate, the transport of which is prohibited except when approved by the Associate Administrator. In addition, there are over 300 numeric codes provisions. The objects must be secured to the flat car, motor vehicle, intermodal container, or unitized by steel banding to wooden runners or pallets and the units secured to the flat car, motor vehicle, or freight container to prevent shifting, including relative motion between the objects, under conditions normally incident to transportation. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. 13 The words Inhalation Hazard shall be entered on each shipping paper in association with the shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. B49 Tanks equipped with interior heater coils are not authorized. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% nitrogen (by dry mass). A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas contained therein. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. 150 This description may only be used for ammonium nitrate-based fertilizers. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. b. Be ASME Code (U) stamped for 100% radiography of all pressure-retaining welds; b. 131 This material may not be offered for transportation unless approved by the Associate Administrator. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corrosion-resistant phenolic lining are authorized for stabilized benzyl chloride if tested and certified to the Packing Group I performance level at a specific gravity of not less than 1.8. Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. If a tank car tank is equipped with a non-reclosing pressure relief device, the rupture disc must be perforated with a 3.2 mm (0.13 inch) diameter hole. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. Liquefied compressed gases are assigned to portable tank instruction T50. For transportation by aircraft, the provisions of 173.159(b)(2) apply. Orientation markings as described in 172.312(a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. If a vehicle is powered by a flammable liquid and a flammable gas internal combustion engine, it must be described using Vehicle, flammable gas powered. This includes hybrid electric vehicles powered by both an internal combustion engine and wet, sodium or lithium batteries installed. When a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. N25 Steel single packagings are not authorized. This entry may not be used for ammonium nitrate for which a proper shipping name already exists in the 172.101 Hazardous Materials Table, including ammonium nitrate mixed with fuel oil or any other commercial grade of ammonium nitrate (e.g., ammonium nitrate fertilizer). Packagings of other material constructed with a small amount of metal must be designed such that the hazardous material does not contact the metal. TP26 The heating device must be exterior to the shell. c. The cylinders are collected and transported by a private or a contract carrier for reconditioning, reuse or disposal. When chemical stabilization is employed, the person offering the material for transport shall ensure that the level of stabilization is sufficient to prevent the material as packaged from dangerous polymerization at 50 C (122 F). TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). Batteries contained in devices must be securely installed. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. Specification 110A500W tanks must be stainless steel. 155 Fish meal, fish scrap and krill meal may not be transported if the temperature at the time of loading either exceeds 35 C (95 F), or exceeds 5 C (41 F) above the ambient temperature, whichever is higher. 146 This description may be used for a material that poses a hazard to the environment but does not meet the definition for a hazardous waste or a hazardous substance, as defined in 171.8 of this subchapter, or any hazard class, as defined in part 173 of this subchapter, if it is designated as environmentally hazardous by another Competent Authority. will bring you to those results. TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. A stimulating mechanism must be used to initiate one article in the middle of the packaging. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. N82 See 173.115 of this subchapter for classification criteria for flammable aerosols. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. 50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting the classification criteria of Division 1.4 are not regulated for domestic transportation. B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. The material is packaged in a DOT Specification 4BW240 cylinder, or in a DOT-51 portable tank. 173 For adhesives, printing inks, printing ink-related materials, paints, paint-related materials, and resin solutions which are assigned to UN3082, and do not meet the definition of another hazard class, metal or plastic packaging for substances of packing groups II and III in quantities of 5 L (1.3 gallons) or less per packaging are not required to meet the UN performance package testing when transported: a. a. B26 Tanks must be insulated. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. All special provision B16 The lading must be completely covered with nitrogen, inert gas or other inert materials. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. N32 Aluminum materials of construction are not authorized for single packagings. TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). Except when approved by the Associate Administrator, these items may only contain hazardous materials for which exceptions are referenced in Column (8) of the 172.101 Table and are provided in part 173, subparts D and G, of this subchapter. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. d. Except for transportation by aircraft, neutron radiation detectors and radiation detection systems containing such detectors transported in accordance with paragraph a of this special provision are not subject to the labeling and placarding requirements of part 172 of this subchapter. 237 Batteries, dry, containing potassium hydroxide solid, electric storage must be prepared and packaged in accordance with the requirements of 173.159(a) and (c). 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. 5101-5128, 44701; 49 CFR 1.81, 1.96 and 1.97. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. This training must be documented in training records required by 172.704(d). Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the requirements of Subpart F of Part 172 [172.502(c)]. c. The time between offering the material for transportation at the point of origin, and unloading the material at the destination does not exceed 48 hours. 48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Organization and Purpose No more than four bottles, securely closed with threaded caps, may be packed in each box. What is Column 7 of the hazardous materials Table? The table below gives the various types of Lead alloy solders. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. Get the latest updates, news, and regulations for HazMat Transport and Waste Management. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. B8 Packagings shall be made of nickel, stainless steel, or steel with nickel, stainless steel, lead or other suitable corrosion resistant metallic lining. If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. In accordance with Special Provision 8 in 172.102, which is referenced in Column 7 of the Hazardous Materials Table (HMT; 172.101) for the entry "UN3082, Environmentally hazardous substance, liquid, n.o.s.," a hazardous substance that is not a hazardous waste may be shipped under the shipping description "Other regulated substances . (7) Special Provisions (172.102) IB8, IP2, IP4 (b) Description of codes for special provisions. These articles must be tested in accordance with Test series 6(c) of Part I of the UN Manual of Tests and Criteria (incorporated by reference; see 171.7 of this subchapter), with no explosion of the device, no fragmentation of device casing or pressure vessel, and no projection hazard or thermal effect that would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity. Test of type 3(c) is not required. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended. Column 4 specifies the applicability of 178.275(g)(3) of this subchapter for the pressure relief devices. PDF 171.26 49 CFR Ch. I (10-1-11 Edition) - GovInfo 159 This material must be protected from direct sunshine and kept in a cool, well-ventilated place away from sources of heat. When portable tank instruction T75 is referenced in Column (7) of the 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of 178.277 of this subchapter. (3) Damage to terminals. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. For UN identification numbers 3531, 3532, 3533, and 3534, IBCs must be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the IBCs in the event of loss of stabilization. Cargo heaters must be reverse refrigeration (heat pump) units. 57 Maneb or Maneb preparations stabilized against self-heating need not be classified in Division 4.2 when it can be demonstrated by testing that a volume of 1 m3 of substance does not self-ignite and that the temperature at the center of the sample does not exceed 200 C, when the sample is maintained at a temperature of not less than 75 C 2 C for a period of 24 hours, in accordance with procedures set forth for testing self-heating materials in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter).

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